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There is now a CONTENT FREEZE for Mercury while we switch to a new platform. It began on Friday, March 10 at 6pm and will end on Wednesday, March 15 at noon. No new content can be created during this time, but all material in the system as of the beginning of the freeze will be migrated to the new platform, including users and groups. Functionally the new site is identical to the old one. webteam@gatech.edu
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Microdroplet Mass Spectrometry for Lipid Isomer Analysis and Accelerated Discovery of Transition Metal Catalysis
Microdroplet chemistry has received increasing attention for accelerated reactions at the air/solution interface in recent years. However, a large and significant category of reactions not demonstrated in microdroplets is the electrochemical reaction. This talk will discuss our progress toward microdroplet electrochemical strategies which include (i) a voltage-controlled interfacial microreactor that allows acceleration of electrochemical reactions for the first time; (ii) novel interfacial electrochemical reactions that address various long-standing isomeric problems in lipid isomer analysis; (iii) novel mass spectrometry screening platform that uses picomole-scale anodic corrosion of transition metal electrodes (e.g., Pd) to enable the rapid discovery of transition metal catalysis.