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There is now a CONTENT FREEZE for Mercury while we switch to a new platform. It began on Friday, March 10 at 6pm and will end on Wednesday, March 15 at noon. No new content can be created during this time, but all material in the system as of the beginning of the freeze will be migrated to the new platform, including users and groups. Functionally the new site is identical to the old one. webteam@gatech.edu
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Atlanta, GA | Posted: February 8, 2017
Allison Tolbert, an RBI fellow and ChBE Ph.D. candidate and graduate research assistant was recently featured on the cover of Energy Science & Engineering. The cover art was based on a review paper title, "Advances in understanding the surface chemistry of lignocellulosic biomass via time-of-flight secondary ion mass spectrometry."
The research was co-published with Dr. Art Ragauskas.
As the title indicates, it is a literature review of the ways ToF-SIMS can help researchers characterize biomass.
Characterizing the surface of biomass is often overlooked in pretreatment and microbial studies. Traditionally, analysis of the biomass bulk chemistry occurs to determine the impact a specific treatment has on the sample. Many pretreatments are used to help overcome the biomass recalcitrance prior to enzymatic hydrolysis. While most enzymes and microorganisms need to bind to the biomass surface, the surface is not a typically analyzed.
Time-of-flight secondary ion mass spectrometry (ToF-SIMS) is a powerful tool capable of analyzing the lignocellulosic ions ejected from the biomass surface. Normalized ion intensities of cellulose, lignin, and even polysaccharides further our understanding of the chemistry changes on the surface. The ToF-SIMS can also spatially map these ion intensities in the plant cell wall.
The analysis of lignocellulosic biomass by ToF-SIMS has increased over the last 12 years. Various chemical pretreatment, biological treatment, and genetic modification studies have used this technique to provide information about the surface chemistry of the sample in addition to tradition bulk analysis data. This information along with sample preparation, details on the instrument, and lignocellulosic secondary ions are all covered in the review article. The full article can be read here.