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There is now a CONTENT FREEZE for Mercury while we switch to a new platform. It began on Friday, March 10 at 6pm and will end on Wednesday, March 15 at noon. No new content can be created during this time, but all material in the system as of the beginning of the freeze will be migrated to the new platform, including users and groups. Functionally the new site is identical to the old one. webteam@gatech.edu
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While we would like to avoid frustration in our daily lives, frustration in condensed matter produces novel phenomena with important consequences. Materials that are geometrically frustrated cannot minimize the energy of every particle-particle interaction, even in their ground state; materials that are kinetically frustrated are trapped out of equilibrium, i.e., they cannot reach their ground state. In this talk I will review a series of experiments I have performed investigating the role of frustration in the assembly and phase behavior of colloidal systems. By tuning particle size, shape, and confinement, I systematically varied the degree of frustration in each experiment. This controlled approach enabled me to create geometrically frustrated colloidal "antiferromagnets," to observe the competition between crystallization and vitrification, and to learn how glasses age. These concepts also appeared in other non-equilibrium soft condensed matter experiments, from materials assembled on the surface of drying drops, to the directed assembly of protein-based structures.
